A new three-dimensional terbium-carboxylate framework possessing Tb-2 and Tb-4 clusters: Synthesis, structure, luminescent and magnetic properties

作者：Shi, Wen-Juan; Hou, Lei^*; Zhao, Wen; Wu, Ling-Yue; Wang, Yao-Yu; Shi, Qi-Zhen

来源：Inorganic Chemistry Communications, 2011, 14(12): 1915-1919.

DOI：10.1016/j.inoche.2011.09.010

• Metal-organic framework
• Lanthanide
• Topology
• Luminescence

A new three-dimensional terbium-carboxylate framework [Tb4L3(H2O)(9)]center dot 7H(2)O (1) [(H4L = 4,4'-(hexafluoroisopropylidene)diphthalic acid)] has been hydrothermally synthesized and structurally characterized. The framework contains Tb-2 and Tb-4 clusters, and exhibits an unprecedented 4-nodal (3,4,5,8)-connected topology. In addition, the thermogravimetric analysis, luminescent and magnetic properties were investigated.

• 单位
  西北大学