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摘要
A chiral helical coordination polymer [Ag(pmta)]n (1) was prepared by the reaction of the asymmetric organic spacer 2-pyrimidylthioacetic acid (Hpmta) with silver(I) acetate. Complex 1 has a hetero-chiral coaxial helical structure, which is further extended into a 2D network structure by various supramolecular interactions. Furthermore, complex 1 exhibits strong fluorescence emission in the solid state and modest power second-harmonic-generation (SHG) efficiency at room temperature.
- 出版日期2012-3
- 单位厦门大学; 中国科学院福建物质结构研究所; 山东科技大学
