A twofold interpenetrating 3D Keggin-based Ag(I) complex based on a flexible bis-pyridyl-bis-amide

作者：Wang Xiuli^*; Xu Chuang; Lin Hongyan; Liu Guocheng; Luan Jian; Chang Zhihan; Tian Aixiang

来源：Journal of Coordination Chemistry, 2013, 66(8): 1451-1458.

DOI：10.1080/00958972.2013.783697

• Keggin polyoxometalate
• Metal-organic complex
• Interpenetrating network
• Flexible bis-pyridyl-bis-amide ligand

A Keggin-type polyoxometalate (POM)-based complex, [Ag-5(L)(3) (H2O)(2)]center dot 6H(2)O (1) (L=N,N-bis(3-pyridinecarboxamide)-1,2-ethane), has been hydrothermally synthesized. Compound 1 shows a 3D+3D interpenetrating network with a (3,4,4,4)-connected (4x6(2))(2)(4(2)x6(2)x8(2))(6(5)x8)(2) topology, and it represents the first example of interpenetrating POM-based complex based on flexible bis-pyridyl-bis-amide ligands. Moreover, the electrochemical behavior and luminescence of 1 have been investigated.

• 出版日期2013-4-1
• 单位渤海大学