H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex

作者:Iluc Vlad M; Fedorov Alexey; Grubbs Robert H*
来源:Organometallics, 2012, 31(1): 39-41.
DOI:10.1021/om201049p

摘要

A PNP-pincer iridium dihydride performs the HID exchange between aromatic substrates and tertiary hydrosilanes and D2O or C6D6. Complete incorporation of deuterium into sterically accessible C-ar-H and Si-H bonds was observed at a moderate temperature of 80 degrees C.

  • 出版日期2012-1-9