Diverse reactions of sterically-protected 1,3-diphosphacyclobutane-2,4-diyls with hydride

作者:Ito Shigekazu*; Miura Joji; Morita Noboru; Yoshifuji Masaaki; Arduengo Anthony J III
来源:Dalton Transactions, 2010, 39(35): 8281-8287.
DOI:10.1039/c0dt00532k

摘要

Hydride-induced elimination of resonance stabilized substituents from a phosphorus center of 1,3-diphosphacyclobutane-2,4-diyls leads to the formation of versatile cyclic phosphaallyl anions that are useful for the construction of various electrophile-modified biradical species.

  • 出版日期2010