A Au(I)-Precatalyst with a Cyclopropenium Counterion: An Unusual Ion Pair

作者:Mir Roya; Dudding Travis*
来源:Journal of Organic Chemistry, 2016, 81(6): 2675-2679.
DOI:10.1021/acs.joc.6b00241

摘要

The synthesis and X-ray crystal structure of a novel Au(I)-precatalyst applied to intermolecular alkyne hydroamination is reported. Density functional theory (DFT) calculations revealed the cyclopropenium counterion of this Au(I)-precatalyst imparts stability through H-bonding and other noncovalent interactions.

  • 出版日期2016-3-18