Direct access to polycyclic peripheral diepoxy-meso-quinone derivatives from acene catalytic oxidation

作者：Costa Paula^*; Linhares Margarida; Rebelo Susana L H; Neves M Graca P M S; Freire Cristina

来源：RSC Advances, 2013, 3(16): 5350-5353.

DOI：10.1039/c3ra23407j

The unprecedented epoxidation on the peripheral positions of tetracene and pentacene with hydrogen peroxide-urea adduct catalyzed by the metalloporphyrin [Mn(TDCPP)Cl] is reported under mild conditions, affording the direct polyfunctionalization of the acenes to anti-diepoxy-meso-quinone derivatives.

• 出版日期2013