μ4-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2Fe -Fe)

作者：Shi, Yao-Cheng^*; Cheng, Huan-Ren; Yuan, Li-Min; Li, Qian-Kun

来源：Acta Crystallographica Section E-Structure Reports Online, 2011, 67: M1534-+.

DOI：10.1107/S1600536811041936

The fused bis-butterfly-shaped title compound, [Fe-4(CS4)-(CO)(12)], possesses an orthothiocarbonate (CS44-) ligand that acts as a bridge between two Fe-2(CO)(6) units. A short intramolecular S center dot center dot center dot S contact [2.6984 (8) and 2.6977 (8) angstrom] occurs in each S2Fe2(CO)(6) fragment.

• 出版日期2011-11
• 单位扬州大学