Aromatic perfluoroalkylation with metal complexes in electrocatalytic conditions

作者:Khrizanforov Mikhail; Gryaznova Tatyana; Sinyashin Oleg; Budnikova Yulia*
来源:Journal of Organometallic Chemistry, 2012, 718: 101-104.
DOI:10.1016/j.jorganchem.2012.06.032

摘要

A one-step catalytic method for aromatic perfluoroalkylation with electrochemically reduced metal complexes under mild conditions with decisive role of the sacrificial anode metal ion has been developed. Cross-coupling is successful with bromo- and iodo-benzene and perfluoroalkyl iodide and number of cobalt and nickel complexes.

  • 出版日期2012-11-1