Hydrogenation of Phenol Using Silica-Supported Pd and PdAu Catalysts in the Presence of H-2 and O-2

作者:Okada Shusuke; Fujiwara Kensei; Kamegawa Takashi; Mori Kohsuke; Yamashita Hiromi*
来源:Bulletin of the Chemical Society of Japan, 2012, 85(9): 1057-1059.
DOI:10.1246/bcsj.20120118

摘要

2-Cyclohexen-1-one can be synthesized from phenol using silica-supported Pd catalyst by hydrogenation under coexisting hydrogen and oxygen gases. The effects of hydrogen and oxygen ratio, solvent, and alloying Pd with Au were investigated. Similar transformations toward corresponding cyclic enones were observed in other phenolic compounds.

  • 出版日期2012-9-15