Kinetics Study of the Synthesis of Butyl(2-azidoethyl)nitramine from the Reaction of 2[Butyl(nitro)amino]ethyl Nitrate with Sodium Azide

作者：Chen Xiaowei^*; Zhan Zujin; Li Purui; Ge Zhongxue; Lei Ming

来源：Acta Chimica Sinica, 2011, 69(20): 2523-2526.

• 2-[butyl(nitro)amino]ethyl nitrate (BuNENA)
• butyl(2-azidoethyl)nitramine (BuAENA)
• azidation
• high performance liquid chromatography (HPLC)
• reaction kinetics

The reaction of 2-[butyl(nitro)amino]ethyl nitrate (BuNENA) with sodium azide is a classical method for synthesis of butyl(2-azidoethyl)nitramine (BuAENA). The kinetics of this reaction was investigated at 62, 70 and 80 degrees C. The concentration of BuNENA in reaction process were determined by high performance liquid chromatography (HPLC) and the reaction rate constants were obtained by fitting the experimental data. The results showed that the overall reaction was of the second-order and the order of reaction for 2-[butyl(nitro)amino]ethyl nitrate and sodium azide was first-order for each, the apparent activation energy was 85.06 kJ.mol(-1). It was demonstrated that the velocity of the reaction was greatly influenced by concentration of reactants and reaction temperature.

• 出版日期2011-10-28
• 单位西安近代化学研究所; 浙江大学