A Convenient Solvothermal Synthesis Route to Metal Phosphides with a Shape of Hollow Nanospheres

作者:Bao Keyan; Liu Shuzhen; Cao Jie; Liang Jiangbo; Zhu Yongchun; Hu Xiaobo; Zhu Lingling; Liu Xiaoyan; Qian Yitai*
来源:Journal of Nanoscience and Nanotechnology, 2009, 9(8): 4918-4923.
DOI:10.1166/jnn.2009.1267

摘要

InP hollow nanospheres with an average size of 550 nm and shell thickness of about 110 nm were solvothermally synthesized in EA (ethanolamine)-H(2)O binary solution at 190 degrees C for 36 h. The shells of InP hollow nanospheres were composed of small nanoparticles. The similar route has been extended to prepare Cd(3)P(2), Cu(3)P and Sn(4)P(3) hollow nanospheres in 150-190 degrees C for 24-36 h.