A Propanediamine-Bridged Dinuclear Iron(III) Complex: Synthesis, X-ray Analyses, Spectral Studies, and Magnetic Properties

作者：Feng, X.^*; Li, S. H.; Sun, Q. Q.; Lei, P. P.; Xie, C. Z.

来源：Russian Journal of Coordination Chemistry, 2011, 37(5): 377-381.

DOI：10.1134/S1070328411040038

• SALEN-TYPE
• DICYANAMIDE
• LIGANDS

A new propylenediamine-bridged diunclear complex formulated as [Fe-2(Salpn)(3)] (I) (pn = 1,2-propylenediamine, H(2)Salpn = N,N'-bis(salicylaldehyde)propylenediamine Schiff base) has been prepared from the template synthesis by the reaction of 1,2-propylenediamine with salicylaldehyde in the presence of the iron(III) salt. The metal centers adopt a slightly distorted octahedral geometry, and the Salpn ligands act in both bridging and chelating modes to form a dinuclear complex with the six-membered chelate rings. The magnetic susceptibility investigation for I indicates the presence of very weak antiferromagnetic coupling between the Fe3+ cations through the propylenediamine bridge.

• 出版日期2011-5
• 单位天津医科大学; 洛阳师范学院