Processing and characterization of A-site deficient [(Ca, Sr) (x) (La, Nd)(2/3-2x/3)]TiO3 dielectric ceramics

作者：Saleem Muhammad^*; Iqbal Yaseen; Qin Shan; Wu Xiang; Ali Shahid; Zhu Feng

来源：Journal of Materials Science: Materials in Electronics , 2014, 25(12): 5282-5287.

DOI：10.1007/s10854-014-2302-7

A-site deficient perovskite ceramics in the [(Ca, Sr) (x) (La, Nd)(2/3-2x/3)]TiO3 (x = 0.1-0.9) system were prepared by a mixed-oxide solid state sintering route. Synchrotron X-ray diffraction and Raman spectroscopy revealed a tetragonal (I4/mcm) symmetry for the compositions with x = 0.1-0.7 and orthorhombic (Pbnm) symmetry for the x = 0.8 and 0.9 compositions. The grain size increased with an increase in x up to 0.7 and then decreased upon further increase in x to 0.8 and 0.9. The optimum microwave dielectric properties (epsilon(r) similar to 48, Q x f = 3,664 GHz and tau (f) similar to +61 GHz) were recorded for the compositions with x = 0.1.

• 出版日期2014-12
• 单位北京大学