摘要

We report an unconventional ZIF-8 based supramolecular MOF (supraMOF) material, which is straightforwardly synthesised by leveraging the high concentration reaction (HCR) approach. Akin to traditional low-molecular-weight gels (LMWG), we show that mechano-stimulus responsive behaviour can be achieved through a reversible and fast sol-gel conversion mechanism. Remarkably, the supraMOF gel consists of 2D nanoplates of ZIF-8 with a reduced crystal symmetry.

  • 出版日期2017-8-7