Diffusive transport through surface functionalized nanoporous alumina membranes by atomic layer deposition of metal oxides

作者：Vega V^*; Gelde L; Gonzalez A S; Prida V M; Hernando B; Benavente J

来源：Journal of Industrial and Engineering Chemistry, 2017, 52: 66-72.

DOI：10.1016/j.jiec.2017.03.025

• Nanoporous alumina membranes
• ALD surface coating
• SEM analysis
• Membrane potentials
• Permselectivity

Changes associated to surface functionalization of nanoporous alumina membranes by atomic layer deposition (ALD) of metal oxides (Al2O3, SiO2, TiO2, Fe2O3, ZnO) are presented. ALD modification of the alumina membranes reveals a reduction up to 25-35% in porosity, and confirms the presence of the metal oxide layer coating the pores. Its effect on the membrane permselectivity and other characteristic transport parameters was determined from membrane potential measurements, being correlated with changes in morphology and physic-chemical characteristics of the alumina membranes. According to our results, ALD provides a straight-forward and efficient method to adjust membrane performance for specific applications.

• 出版日期2017-8-25