A New Luminescent Zn(II) Coordination Polymer Based on Mixed Ligands of Pyrazine-2,3-Dicarboxylic Acid and 3-Amino-1,2,4-Triazole

作者：Liu, Ya-Ru^*; Liang, Guo-Rui; Wie, Zhi-Xian

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2015, 45(3): 319-322.

DOI：10.1080/15533174.2013.831889

• hydrogen bond
• supramolecular framework
• Zn(II) compound
• 3-dicarboxylic acid
• pyrazine-2

A new luminescent coordination polymer, namely [Zn(pzdc)(AmTAZ)](n) (1 H(2)pzdc = pyrazine-2,3-dicarboxylic acid, AmTAZ = 3-amino-1,2,4-triazole), has been successfully synthesized under hydrothermal conditions. Single-crystal X-ray analysis reveals that 1 is a two-dimensional (2D) layered structure with the terminal AmTAZ ligands dangling up and down the layer. Finally, these 2D layers are further extended into a three-dimensional (3D) supramolecular framework through intermolecular hydrogen bonds.

• 出版日期2015-3-4
• 单位中北大学