Double [3+2]-dimerisation cascade synthesis of bis(triazolyl)bisphosphanes, a new scaffold for bidentate bisphosphanes

作者:Laborde Coralie; Wei Muh Mei; van der Lee Arie; Deydier Eric; Daran Jean Claude; Volle Jean Noel; Poli Rinaldo; Pirat Jean Luc; Manoury Eric*; Virieux David
来源:Dalton Transactions, 2015, 44(28): 12539-12545.
DOI:10.1039/c5dt02197a

摘要

A highly convergent synthesis of bis(triazolylphosphane oxides) was developed by a tandem copper-mediated Huisgen reaction-oxidative coupling. The phosphane oxides were reduced by trichlorosilane and the coordination of the resulting bisphosphanes was studied with various transition metals.

  • 出版日期2015