A Novel 2D Coordination Polymer Constructed from Left- and Right-handed Helical Chains and 4,4'-bipyridine Bridges

作者：Li Zifeng; Guo Lin; Zhang Fuwei; Li Gang^*; Zhu Lu

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2010, 40(10): 734-738.

DOI：10.1080/15533174.2010.522536

• crystal structure
• helical coordination polymer
• synthesis
• thermal property

Treatment of 2-methyl-1H-imidazole-4,5-dicarboxylic acid (H3MIA) with Co(NO3)2 in the presence of 4,4'-bipyridine (4,4'-bipy) under hydrothermal condition, yielded one novel two-dimensional (2-D) coordination polymer [Co(HMIA)(H2O)(4,4'-bipy)0.5]center dot H2On (1). Single-crystal structural study reveals that the complex incorporates alternate left- and right-handed helical chains by 4,4'-bipy linkages. This is the first example of 2-D Co(II) helical coordination polymer with mixed HMIA and 4,4'-bipy ligands. Its thermal properties are also investigated.

• 出版日期2010
• 单位郑州大学