Mechanochemical synthesis of crystalline and amorphous digold(I) helicates exhibiting anion- and phase-switchable luminescence properties

作者：Jobbagy Csaba; Molnar Miklos; Baranyai Peter; Deak Andrea^*

来源：Dalton Transactions, 2014, 43(31): 11807-11810.

DOI：10.1039/c4dt01214c

For the first time, mechanochemical synthesis has been used for the preparation of crystalline and amorphous dinuclear gold(I) helicates, [Au2L2](X)(2) (L = xantphos; X = CF3SO3, SCN, BF4 and PF6), that show anion- and phase-switchable luminescence properties. This solid-state approach provides strategies for developing switchable luminescent materials.

• 出版日期2014-8-21