科研之友
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摘要
Three new Co containing coordination polymers {Co-2(suc)(2)(1, 10 '-phen)2}(n) (1), {Co-2(glu)(2)(1,10 '-phen)(2)}(n) (2), {Co(adip)(1,10 '-phen)(H2O)}(n) (3), have been synthesized under the hydrothermal condition and characterized by elemental analysis, IR, TG analysis and single crystal X-ray diffraction. Complex I exhibits a novel two-dimensional layer framework, in which the bi-nuclear Co clusters are linked by succinic anions. Complex 2 has a one-dimensional chain-like structure. Complex 3 is also a one-dimensional chain-like structure, which is further connected by hydrogen bonds to generate a two-dimensional, layer-like structure. Furthermore, the thermal properties of the above three complexes are studied.
- 出版日期2007-5
- 单位东北师范大学
