Aqueous RAFT/MADIX polymerisation of vinylphosphonic acid

作者：Blidi Issam; Geagea Roland; Coutelier Olivier; Mazieres Stephane; Violleau Frederic; Destarac Mathias^*

来源：Polymer Chemistry, 2012, 3(3): 609-612.

DOI：10.1039/c2py00541g

RAFT/MADIX polymerisation of vinylphosphonic acid (VPA) was controlled in water with an O-ethyl xanthate transfer agent. This represents the first example of reversible deactivation radical polymerisation of a monomer bearing an unprotected phosphonic acid function. Hence, macromolecular engineering of polyphosphonates can now be envisioned by directly polymerising VPA in water.

• 出版日期2012