摘要

A new 2D Cu(I)-based coordination polymer with Lewis basic sites based on pytpy (pytpy = 4'-(4-pyridyl)-3,2':6',3 ''-terpyridine) ligand, [cu(pytpy)(CN)](n)(1), has been synthesized solvothermally and characterized. The photoluminescence property shows that 1 can work as highly sensitive sensors to nitro explosive and Fe3+ by luminescent quenching. This study demonstrated that 1 could be a useful luminescent sensor for metal ions and organic small molecules.