An efficient cleavage of the aryl ether C-O bond in supercritical carbon dioxide-water

作者:Chatterjee Maya*; Ishizaka Takayuki; Suzuki Akira; Kawanami Hajime
来源:Chemical Communications, 2013, 49(40): 4567-4569.
DOI:10.1039/c3cc41522h

摘要

A simple and highly efficient Rh/C catalyzed route for the cleavage of the C-O bond of aromatic ether at 80 degrees C in the presence of 0.5 MPa of H-2 in the scCO(2)-water medium is reported; CO2 pressure and water play a key role under the tested conditions.