Addition of Carbon-Fluorine Bonds to a Mg(I)-Mg(I) Bond: An Equivalent of Grignard Formation in Solution

作者：Bakewell Clare; White Andrew J P; Crimmin Mark R

来源：Journal of the American Chemical Society, 2016, 138(39): 12763-12766.

DOI：10.1021/jacs.6b08104

Addition of the carbon-fluorine bond of a series of perfluorinated and, polyfluorinated arenes across the Mg-Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon-magnesium bond and a new fluorine-magnesium bond and is analogous to Grignard formation in homogeneous solution.

• 出版日期2016-10-5