A high nuclearity mixed valence {Mn-32} complex

作者：Langley Stuart K; Stott Rachel A; Chilton Nicholas F; Moubaraki Boujemaa; Murray Keith S^*

来源：Chemical communications, 2011, 47(22): 6281-6283.

DOI：10.1039/c1cc00035g

A mixed-valence {Mn-32} complex, containing Mn-II, Mn-III and Mn-IV ions, with a probable S = 5 ground state, utilizes pivalate as a capping ligand and a variety of oxo-type bridging ligands. AC susceptibility data on fresh samples suggest that the Mn-32 complex is one of the largest nuclearity single molecule magnets found to date.

• 出版日期2011