Acid-base-driven interconversion between a mononuclear complex and supramolecular coordination polymers in a terpyridine-functionalized dioxocyclam ligand

作者：Gasnier Aurelien; Barbe Jean Michel; Bucher Christophe; Denat Franck; Moutet Jean Claude; Saint Aman Eric; Terech Pierre; Royal Guy^*

来源：Inorganic Chemistry, 2008, 47(6): 1862-1864.

DOI：10.1021/ic701584e

A polytopic cyclam-bis-terpyridine ligand has been used to accomplish an acid-base-triggered formation of either a mononuclear neutral complex or metallopolymers with Cu2+ ions. A controlled interconversion between these two forms was achieved through the reversible displacement of a Cu2+ cation from the macrocycle to the terpyridine units.

• 出版日期2008-3-17
• 单位中国地震局