An activation energy approach to analysing non-Newtonian slurry viscosities with application to a suspension of starch in a carboxymethylcellulose solution

作者：Chandler H D^*

来源：Powder Technology, 2014, 268: 368-372.

DOI：10.1016/j.powtec.2014.08.058

• Viscosity
• Suspensions
• Shear thinning
• Activation energy
• Activation entropy

Many suspensions of practical importance exhibit non-Newtonian fluid behaviour. For a given particle concentration and temperature, these often have relative viscosities that vary with shear rate and this necessitates modifications to the frequently applied Krieger-Dougherty equation. A simple way to analyse viscosity data is by consideration of the activation energy. It is demonstrated as an example of the approach that the properties of a non-Newtonian suspension of starch in a carboxymethylcellulose solution may be described simply in terms of the activation entropy which can be interpreted as a semi- empirical measure of the degree to which structural re-arrangement occurs during flow.

• 出版日期2014-12