摘要
Despite recent advances in main group N-heterocyclic carbene (NHC) coordination chemistry, gallium hydrides remain, in large part, an unexplored area of research. In this paper we outline efficient routes to azide- and amido-functionalized gallium hydrides such as NHC center dot GaH2N3 and NHC center dot GaH2N(SiMe3)(2) and explore these species as potential precursors to HGaNH complexes and bulk gallium nitride (GaN).
- 出版日期2017-2-7