Azido- and amido-substituted gallium hydrides supported by N-heterocyclic carbenes

作者:Swarnakar Anindya K; Ferguson Michael J; McDonald Robert; Rivard Eric
来源:Dalton Transactions, 2017, 46(5): 1406-1412.
DOI:10.1039/c6dt04595brsc.li/dalton

摘要

Despite recent advances in main group N-heterocyclic carbene (NHC) coordination chemistry, gallium hydrides remain, in large part, an unexplored area of research. In this paper we outline efficient routes to azide- and amido-functionalized gallium hydrides such as NHC center dot GaH2N3 and NHC center dot GaH2N(SiMe3)(2) and explore these species as potential precursors to HGaNH complexes and bulk gallium nitride (GaN).

  • 出版日期2017-2-7

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