Amine-imine compounds of nickel(II) and copper(II) incorporating 1,2-ethanediamine and 1,3-propanediamine

作者：Curtis Neil F^*; Gladkikh Olga P; Robinson Ward T; Butcher Raymond J

来源：Inorganica Chimica Acta, 2017, 457: 90-94.

DOI：10.1016/j.ica.2016.11.018

• Nickel(II) compound
• Copper(II) compound
• Crystal structures
• [2,8,8,10-Tetramethyl-3,7,11-triazatridec-2,10-diene-13-amine)nickel(II) ]
• [(15-Amino-4,4,9,9,11-pentamethyl-5,8,12-triazatetradec-11-ene-2-one)cop per(11)]

Reaction with acetone of [M(en)(tmd)](ClO4)(2) (en = 1,2-ethanediamine, tmd = 1,3-propanediamine) for M = Ni(II) forms 7RS-(2,8,8,10-tetramethy1-3,7,11-trimethyltridec-2,10-diene-13-amine)nickel(II) perchlorate with square-planar Ni(II). For M = Cu(II) the reaction forms 5RS,8RS-(15-amino-4,4,9,9,11-pentamethyl-5,8,12-tetraazapentadec-11-ene-2-one)copper(II) perchlorate 0.33 water with a N4O pentadentate ligand. The structures of these products are reported.

• 出版日期2017-3-1