A novel chiral 3D supramolecular framework based on organooxotin cluster

作者：Li Shun Li; Ping Guang Ju; Liu Jie; Ma Jian Fang^*; Su Zhong Min

来源：Inorganic Chemistry Communications, 2008, 11(2): 220-224.

DOI：10.1016/j.inoche.2007.11.009

• organotin(IV)
• cluster
• chiral
• topology

A novel triorganotin compound, namely [(Ph3Sn)(3)(CO3)(EtOH)(3)] center dot(nth) center dot Cl center dot H2O (1), exhibits the novel chiral 3D supramolecular structure with a (10,3) topology based on the organooxotin cluster, in which ntb ligand and [(Ph3Sn)(3)(CO3)(EtOH)(3)](+) unit act as three-connected nodes and link each other through O-H center dot center dot center dot N bonds.

• 出版日期2008-2
• 单位东北师范大学