摘要

The enhancement of chromatographic separate selectivity based on the molecular recognition of calixarenes is successful application of supramolecular chemistry in separation sciences. The new progress in the application of calixarenes for high performance liquid chromatography (HPLC), capillary electrophoresis (CE) and capillary electrochromatography (CEC) is reviewed, emphasizing on the preparation, separation mechanism and application of the novel materials containing calixarenes.