DECOMPOSITION KINETICS OF GASEOUS OZONE IN PEANUTS

作者:de Alencar Ernandes R*; Faroni Leda R D; Martins Marcio A; da Costa Andre R; Cecon Paulo R
来源:Engenharia Agricola, 2011, 31(5): 930-939.
DOI:10.1590/s0100-69162011000500011

摘要

This study was conducted to evaluate the decomposition kinetics of gaseous ozone in peanut grains. This evaluation was made with 1-kg peanut samples, moisture contents being 7.1 and 10.5% wet basis (w.b.), placed in 3-liter glass containers. The peanut grains were ozonated at the concentration of 450 mu g L-1, at 25 and 35 degrees C, with gas flow rates of 1.0 and 3.0 L min(-1). Time of saturation was determined by quantifying the residual concentration of ozone after the gas passed through the grains to constant mass. The decomposition kinetics of ozone was evaluated after the grain mass was ozone-saturated. For the peanut grains whose moisture content was 7.1% (w.b.), at 25 and 35 degrees C and with flow rates of 1.0 and 3.0 L min(-1), the values obtained for time of saturation of gaseous ozone ranged between 173 and 192 min; the concentration of saturation was approximately 260 mu g L-1. For the grains whose moisture content was 10.5% (w.b.), a higher residual concentration of gaseous ozone was obtained at 25 degrees C, that of 190 mu g L-1. As regards the half-life of ozone, the highest value obtained was equivalent to 7.7 min for grains ozonated at 25 degrees C, while for those with moisture content of 10.5% at 35 degrees C, half-life was 3.2 min. In the process of ozone decomposition in peanut grains, temperature was concluded to be the key factor. An increase of 10 degrees C in the temperature of the grains results in a decrease of at least 43% in the half-life of ozone.

  • 出版日期2011-10