Alkoxy substituted halogenated closo-dodecaborates as anions for ionic liquids

作者:Jenne Carsten; Kirsch Christoph
来源:Dalton Transactions, 2015, 44(29): 13119-13124.
DOI:10.1039/c5dt01633a

摘要

Alkoxy substituted halogenated closo-dodecaborate anions [B12X11OR]2− (X = Cl, Br; R = alkyl) have been synthesized and fully characterized. Thermal analyses were carried out to reveal their properties for possible applications in ionic liquids. The new salt [C6mim]2[B12Cl11O-propyl] is an elusive example of an ionic liquid containing a doubly charged anion.

  • 出版日期2015