A luminescent two-fold interpenetrated pillared-layer metal-organic framework for highly selective and sensitive sensing of Fe3+

作者：Zhu, Xian-Dong^*; Zhang, Kun; Zhou, Wei-Xiang; Li, Qing-Hai; Fu, Ying-Qiang; Liu, Rong-Mei; Qian, Gui-Xiang

来源：Inorganic Chemistry Communications, 2016, 73: 90-93.

DOI：10.1016/j.inoche.2016.10.009

• Metal-organic framework
• Aromatic sulfonic ligand
• Interpenetrated pillared-layer structure
• Luminescent sensor

A luminescent three-dimensional metal-organic framework generally formulated as [Zn-2(OH)(sip)(bpe)(H2O)]H2O (1), has been hydrothermally synthesized and characterized. It represents a new two-fold interpenetrated pillared-layer framework with (6(3))(6(9) center dot 8) topology constructed from pi-electron-rich rigid ligand 5-sulfoisophthalic acid coupled with auxiliary ligand 1,2-bis(4-pyridyl)ethane. Interestingly, the strong emission of 1 could be quenched efficiently by trace amounts of Fe3+ at room temperature, even in the presence of other competing analogues, which indicated that 1 can serve as an excellent sensor for specific selective identification and quantification of Fe3+.

• 出版日期2016-11
• 单位中国科学院福建物质结构研究所; 安徽工程大学