Amine influence in vanadium-based ethylene polymerisation pro-catalysts bearing bis(phenolate) ligands with 'pendant' arms

作者：Lorber Christian^*; Despagnet Ayoub Emmanuelle; Vendier Laure; Arbaoui Abdessamad; Redshaw Carl

来源：Catalysis Science & Technology, 2011, 1(3): 489-494.

DOI：10.1039/c1cy00089f

Two families of vanadium complexes bearing diphenolate ligands with different 'pendant' arms have been screened under various conditions for the polymerisation behaviour of ethylene. The presence of a bound amine arm was found to favour enhanced thermal stability.

• 出版日期2011