A linear rod-packing coordination polymer constructed from a non-linear dicarboxylate and the [Zn4O](6+) cluster

作者:Keltie Sam M; Gale Philip A; Light Mark E; Tromp Moniek*
来源:Journal of Coordination Chemistry, 2013, 66(17): 3058-3062.
DOI:10.1080/00958972.2013.824075

摘要

A 1-D coordination polymer, [Zn4O(1,2-BDC)(3)](n) (1,2-BDC=1,2-benezendicarboxyate), has been synthesized under solvothermal conditions and structurally characterized by single-crystal X-ray diffraction. The coordination polymer contains [Zn4O](6+) clusters with a central (4)-oxygen tetrahedrally coordinated by four Zn2+ ions, which stack into a linear rod connected by 1,2-BDC units.

  • 出版日期2013-9-10