The crucial role of a Ni(I) intermediate in Ni-catalyzed carboxylation of aryl chloride with CO2: a theoretical study

作者：Sayyed Fareed Bhasha; Tsuji Yasushi; Sakaki Shigeyoshi^*

来源：Chemical communications, 2013, 49(91): 10715-10717.

DOI：10.1039/c3cc45836a

In Ni(0)-catalyzed carboxylation reaction of aryl chloride with CO2, the formation of a Ni(I) species is crucial, because the CO2 insertion into the Ni(I)-Ph bond easily occurs but that into the Ni(II)-Ph bond cannot. This is a key point of this successful carboxylation reaction.

• 出版日期2013