Air Oxidation of Activated Carbon to Synthesize a Biomimetic Catalyst for Hydrolysis of Cellulose

作者：Shrotri Abhijit; Kobayashi Hirokazu; Fukuoka Atsushi^*

来源：Chemsuschem, 2016, 9(11): 1299-1303.

DOI：10.1002/cssc.201600279

• oxidation
• biomimetic catalyst
• carbon
• carboxylic acid
• cellulose

Oxygenated carbon catalyzes the hydrolysis of cellulose present in lignocellulosic biomass by utilizing the weakly acidic functional groups on its surface. Here we report the synthesis of a biomimetic carbon catalyst by simple and economical air-oxidation of a commercially available activated carbon. Air- oxidation at 450-500 degrees C introduced 2000-2400molg(-1) of oxygenated functional groups on the material with minor changes in the textural properties. Selectivity towards the formation of carboxylic groups on the catalyst surface increased with the increase in oxidation temperature. The degree of oxidation on carbon catalyst was found to be proportional to its activity for hydrolysis of cellulose. The hydrolysis of eucalyptus in the presence of carbon oxidized at 475 degrees C afforded glucose yield of 77% and xylose yield of 67%.

• 出版日期2016-6-8