A naphthyl-substituted pentamethylcyclopentadienyl ligand and its Sm(II) bent-metallocene complexes with solvent-induced structure change

作者：Yatabe Takeshi; Karasawa Masaki; Isobe Kiyoshi; Ogo Seiji; Nakai Hidetaka^*

来源：Dalton Transactions, 2012, 41(2): 354-356.

DOI：10.1039/c1dt11844g

A naphthyl-substituted pentamethylcyclopentadienyl ligand (Cp-Naph = eta(5)-C5Me4CH2C10H7) and its Sm(II) complexes [Sm(Cp-Naph)(2)(THF)(x)] (1: x = 2, 2: x = 0) have been prepared and characterised. The solvent-induced reversible conversion between the di-THF solvated purple complex 1 and the un-solvated dark green complex 2 is presented.

• 出版日期2012