Bonding mode of a new bis-phosphine-borane alkyl ligand to a Rh(I) species

作者：Blug Matthias; Gruenstein Dan; Alcaraz Gilles; Sabo Etienne Sylviane; Le Goff Xavier Frederic; Le Floch Pascal; Mezailles Nicolas^*

来源：Chemical Communications, 2009, (29): 4432-4434.

DOI：10.1039/b907813d

The stoichiometric reaction of [Rh(COD)Cl](2) with the anion resulting from the deprotonation of dppm(BH(3))(2) yielded a new alkyl Rh(I) complex; the coordination modes of the BH(3) groups are discussed on the basis of X-ray data, variable temperature multinuclear NMR experiments and DFT studies.

• 出版日期2009