Antimony-dependent expansion for the Keggin heteropolyniobate family

作者：Zhang, Zhe-Yu; Peng, Jun^*; Shi, Zhen-Yu; Zhou, Wan-Li; Khana, Shifa Ullah; Liu, Hong-Sheng

来源：Chemical Communications, 2015, 51(15): 3091-3093.

DOI：10.1039/c4cc09612f

• STRUCTURAL-CHARACTERIZATION
• PHOTOCATALYTIC PROPERTIES
• SOLID-STATE
• POLYOXONIOBATE
• CLUSTERS
• EVOLUTION
• FRAMEWORK
• HYBRIDS

Nine new Sb-bicapped alpha-Keggin-type heteropolyoxoniobates (HPNb) were synthesized under hydrothermal conditions. Among them, the As-centered HPNb was never reported before, and the two dimer compounds are the biggest isolated HPNbs at present.

• 出版日期2015
• 单位东北师范大学; 白城师范学院; 大庆师范学院