科研之友
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摘要
New heterocyclic compounds characterized by the presence of a diaziridine and an oxaziridine ring directly bound were reported. A first desymmetrization reaction of alpha-diimines using nosyloxycarbamate as aminating agent in a H2O/CH2Cl2 system gives (E)-3-(iminomethyl)diaziridine-1-carboxylates which were further functionalized obtaining the never synthesized before 3-(diaziridin-3-yl)oxaziridines.
- 出版日期2013-8-21
