Applications of Solid-State Ca-43 Nuclear Magnetic Resonance: Superconductors, Glasses, Biomaterials, and NMR Crystallography

作者：Widdifield Cory M

来源：ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 92, ELSEVIER ACADEMIC PRESS INC, 525 B STREET, SUITE 1900, SAN DIEGO, CA 92101-4495 USA, 227-363, 2017.

DOI：10.1016/bs.arnmr.2017.04.006

• Ca-43
• NMR
• Crystallography
• Solid-state
• EFG
• Chemical shift
• Quadrupole
• Biomaterials
• Bone
• Cement

The application of Ca-43 solid-state nuclear magnetic resonance (SSNMR) experiments to probe various materials is reviewed. Methods used to obtain high-quality Ca-43 SSNMR spectra, and the types of information which can be gained by recording Ca-43 NMR spectra, are outlined. Substantial discussion is provided in relation to the classes of materials which have already been studied, at least in part, by Ca-43 SSNMR. This includes, but is not limited to, superconductors, binary and ternary calcium-containing inorganics (and hydrates thereof), silicates, glasses, cements, concretes, clays, phosphates, bones, teeth, calcium-containing organics, and biomaterials. Studies that include the computation of calcium NMR parameters using quantum chemistry methods are discussed in detail, which leads naturally to accounts pertaining to NMR crystallography. This review concludes with brief speculations on the future of Ca-43 SSNMR.

• 出版日期2017