Aminocarbonylation of aryl halides using a nickel phosphite catalytic system

作者:Ju Jinhun*; Jeong Miso; Moon Jeongju; Jung Hyun Min; Lee Sunwoo
来源:Organic Letters, 2007, 9(22): 4615-4618.
DOI:10.1021/ol702058e

摘要

The nickel and phosphite catalytic system with sodium methoxide enables a very efficient aminocarbonylation reaction to be performed between aryl iodides or bromides and N,N-dimethylformamide (DMF). Phosphite ligand 1, which is very stable to air and moisture and, furthermore, inexpensive, afforded the highest reaction yield.

  • 出版日期2007-10-25