摘要

One new self-assembled heterobimetallic complex with the composition CuL-Co(SCN)(4) (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) has been prepared and characterized by IR spectra and elemental analysis. The molecular magnetic properties of the complex were characterized by magnetic susceptibility and presents a antiferromagnetic interaction between the tetraaza macrocycle Cu(II) ions and Co(SCN)(4)(2-) through the thiocyanato-bridged in the complex.