A precise hexagonal octadecanuclear Ag macrocycle with significant luminescent properties

作者：Jin Jin; Wang Weiyin; Liu Yanhua; Hou Hongwei^*; Fan Yaoting

来源：Chemical Communications, 2011, 47(26): 7461-7463.

DOI：10.1039/c1cc12142a

The first hexagonal octadecanuclear Ag macrocycle [Ag-18(TTTMB)(12)](NO3)(18)center dot 30H(2)O has been hydrothermally synthesized. The outside and inner diameters of the unprecedented architecture are about 27.72(13) angstrom and 15.37(7) angstrom, respectively. This complex displays a huge increase in the intensity and lifetime of phosphorescence with decreasing temperature.

• 出版日期2011
• 单位郑州大学