Using platinum-group elements and Au geochemistry to constrain the genesis of podiform chromitites and associated peridotites from the Soghan mafic-ultramafic complex, Kerman, Southeastern Iran

作者：Najafzadeh A R^*; Ahmadipour H

来源：Ore Geology Reviews, 2014, 60: 60-75.

DOI：10.1016/j.oregeorev.2013.12.014

• Iran
• Platinum-group elements
• Podiform chromitites
• Soghan mafic-ultramafic complex
• Supra-subduction zone

The podiform chromite deposit of the Soghan mafic-ultramafic complex is one of the largest chromite deposits in south-east Iran (Esfandagheh area). The Soghan complex is composed mainly of dunite, harzburgite, Iherzolite, pyroxenite, chromitite, wehrlite and gabbro. Olivine, orthopyroxene, and to a lesser extent clinopyroxene with highly refractory nature, are the primary silicates found in the harzburgites and dunites. The forsterite content of olivine is slightly higher in dunites (Fo(94)) than those in harzburgites (Fo(92)) and Iherzolites (Fo(89)). Chromian spinel mainly occurs as massive chromitite pods and as thin massive chromitite bands together with minor disseminations in dunites and harzburgites. Chromian spinels in massive chromitites show very high Cr-numbers (80-83.6), Mg-numbers (62-69) and very low TiO2 content (averaging 0.17 wt.%) for which may reflect the crystallization of chromite from a boninitic magma. The Fe3+-number is very low, down to <0.04 wt.%, in the chromian spinel of chromitites and associated peridotites of the Soghan complex.
PGE contents are variable and range from 80 to 153 pbb. Chromitites have strongly fractionated chondrite-normalized PGE patterns, which are characterized by enrichments in Os, Ir and Rh relative to Pt and Pd. Moreover, the Pd/Ir value which is an indicator of PGE fractionation ranges from <0.08 to 0.24 in chromitite of the Soghan complex. These patterns and the low PGE abundances are typical of ophiolitic chromitites and indicating a high degree of partial melting (about 20-24%) of the mantle source. Moreover, the Pd-N/Ir-N ratios in dunites are unfractionated, averaging 1.2, whereas the harzburgites and Iherzolites show slightly positive slopes PGE spidergrams, together with a small positive Ru and Pd anomaly, and their Pd-N/Ir-N ratio averages 1.98 and 2.15 respectively.
The mineral chemistry data and PGE geochemistry, along with the calculated parental melts in equilibrium with chromian spinel of the Soghan chromitites indicate that the Soghan complex was generated from an arc-related magma with boninitic affinity above a supra-subduction zone setting.

• 出版日期2014-7