A novel route with a Cu(II)-MOF-derived structure to synthesize Cu/Cu2O NPs@graphene: the electron transfer leads to the synergistic effect of the Cu(0)-Cu(I) phase for an effective catalysis of the Sonogashira cross-coupling reactions

作者：Sun, Wei; Gao, Lingfeng^*; Sun, Xu; Zheng, Gengxiu^*

来源：Dalton Transactions, 2018, 47(16): 5538-5541.

DOI：10.1039/c8dt00465j

• CU2O NANOPARTICLES
• SELECTIVITY
• CHEMISTRY
• MECHANISM
• REMOVAL
• LIGANDS

A uniformly dispersed two-phase Cu/Cu2O NPs@graphene was obtained via an innovative "take" and "off" synthesis strategy with a Cu-MOF-derived jacket structure. The electron transfer between the Cu phase and Cu2O phase leads to the synergistic effect of the Cu(0)-Cu(I) phase for an efficient catalysis of the Sonogashira cross-coupling reactions.

• 出版日期2018-4-28
• 单位济南大学