科研之友
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摘要
Achiral and chiral imidazoliophanes were prepared by N-alkylation of chiral imidazole derivatives featuring an alpha-amino acid motif and subsequent double quarternization of the imidazole N3-position of the corresponding precyclophanes. Eight new optically pure imidazoliophanes were synthesized in good yields, whereas the molecular structure of one achiral analogue was confirmed by X-ray analysis.
- 出版日期2010-9
